The Brazil forward was withdrawn in the 12th minute of the Selecao’s 1-1 friendly draw with Nigeria on Sunday.
PSG announced Neymar had an MRI scan on Monday that confirmed the injury, which will be re-evaluated in eight days.
Neymar has played just five games for PSG this season owing to an ankle injury picked up in June.
The ex-Barcelona forward did not make his first appearance until September, having attempted to force a move away from the club he joined for a world-record €222million fee in 2017.
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